After a day I have to say that this album didn't blow me away the way Harmonium did, but it's a solid album nonetheless.
I think it was a little overproduced, but maybe that will help V achieve more "mainstream" popularity. I really wish she didn't change the entire feel of (PY)HOM for the album -- that song worked so well exactly as she sang it at the US Open. The song as recorded on the album is still very good, just not as good as it could have been, in my opinion, had they simplified it.
Home and Heroes & Thieves on the album are superior to the live versions I have heard. I also like The One and don't mind Stevie Nicks's harmonies.
Fools Like Me is also very good and I actually like the arrangement.
As for More Than This, it just sounds too much like a Broadway musical number for me -- feels like I am listening to the soundtrack of Rent.